New Synthetic Method for Industrial Manufacture of Glutaric Dialdehyde

A new synthetic method for the manufacture of glutaric dialdehyde is investigated. Glutaric dialdehyde was prepared by the addition-hydrolysis reaction of benzimidazolium salt with saturated dihalide as the di-Grignard reagent. The yield of glutaric dialdehyde by this method can reach 73%. Both infrared spectra and melting point of the compound were consistent with those reported earlier. Translated from Journal of Northwest University (Natural Science Edition), 2005, 35(2) (in Chinese)     

布尔“复合函数”的Walsh循环谱和自相关函数

本文利用布尔随机变量联合分布的分解式给出了布尔“复合函数”和某布尔函数符合率的分解算式,由此求得了布尔“复合函数”的 Walsh循环谱和自相关函数的计算公式,公式清楚地表明了“复合”所得布尔函数的 Walsh循环谱与起“复合”作用的函数和被“复合”的各函数所有线性组合的 Walsh循环谱之间的关系、“复合”所得布尔函数的自相关函数与起“复合”作用的函数谱和被“复合”的各函数的谱及相关函数之间的关系,这两个公式在布尔函数的密码学性质研究中会有广泛的应用.     

Bis[μ‐1‐(1,10‐phenanthrolin‐2‐yl)‐2‐pyridone]bis{aqua[1‐(1,10‐phenanthrolin‐2‐yl)‐2‐pyridone]cadmium(II)} tetrakis(perchlorate)

In the title centrosymmetric binuclear complex, [Cd₂(C₁₇H₁₁N₃O)₄(H₂O)₂](ClO₄)₄, the Cd^II ion assumes a distorted octahedral geometry. There are π–π stacking interactions between the pyridine and 1,10‐phenanthroline ring systems of adjacent ligands at the same Cd^II centre. Intermolecular hydrogen bonds between the coordinated aqua ligand and the O atom of a keto group connect adjacent complex cations into extended chains. Hydrogen bonds also exist between the complex cations and the perchlorate anions. Compared with the fluorescence spectrum of the organic ligand, the complex displays strong fluorescent emission and an ipsochromic shift of the emission peaks, which may be attributed to the structural character.     

Pulsed laser deposition of atomically flat La1-xSrxMnO3 thin films using a novel target geometry

A new ablation target geometry is presented that was used to produce thin films of La_1-xSr_xMnO₃ grown heteroepitaxially on SrTiO₃ by pulsed reactive crossed-beam laser ablation. The films were grown in order to perform angle-resolved photoelectron spectroscopy, which demands that the surface be atomically flat. In situ and ex situ analysis shows that this condition was met, even after depositing to a thickness of over 100 nm. PACS 61.10.-i; 61.18.Bn; 68.47.Gh; 71.27.+a; 81.15.Fg     

On Two Theorems of Finite Solvable Groups

For a finite group G, let T（G） denote a set of primes such that a prime p belongs to T（G） if and only if p is a divisor of the index of some maximal subgroup of G. It is proved that if G satisfies any one of the following conditions： （1） G has a p-complement for each p∈T（G）; （2）│T（G）│= 2： （3） the normalizer of a Sylow p-subgroup of G has prime power index for each odd prime p∈T（G）; then G either is solvable or G/Sol（G）≌PSL（2, 7） where Sol（G） is the largest solvable normal subgroup of G.     

大米中硒的FI-HG-AAS测定方法研究

研究了原子化器温度、载气流速、KBH4 浓度等条件对流动注射 氢化物发生 原子吸收光谱法 (FI-HG -AAS)测定硒时的影响。建立了FI-HG -AAS测定大米中硒的分析方法。在优化的工作条件下 ,测定硒的最低检测浓度为 0 3 3 μg·L- 1,线性范围为 0～ 5 0 μg·L- 1,相对标准偏差小于 4% ,加标回收率为 94%～ 1 0 2 %。本法克服了传统的间断氢化物发生 原子吸收光谱法分析速度慢、样品耗量大、操作繁琐且因手工进样在进样速度和进样体积上容易带来误差等缺点。方法操作简便、快速 ,灵敏度及自动化程度高 ,已广泛应用于大米及富硒大米中微量硒的测定     

Investigation of charge effects on poling and stability for corona-poled polymer films

The optimal corona-poling temperature of polymer films was accurately determined by measuring the temperature dependence of the in situ second-harmonic (SH) intensity profile under the applied poling electric field. The in situ SH intensity profile was first measured by probing both the surface voltages and the poling currents induced by surface/space charges for the corona-poled polymer films. Moreover, charge effects on the stability of the chromophore orientation were first studied by using the thermally stimulated discharge-current technique. PACS 72.20.Jv; 42.65.Ky; 73.61.Ph; 81.40.Tv     

Envelop solitons in dusty plasmas for warm dust

A nonlinear Schrödinger equation is obtained for the warm dusty plasmas. The modulational instability of envelop soliton is investigated in this paper. Both the temperature of the dust grains and the charge variations of dust grains affect the instability regions of the dusty plasmas. It also affect the amplitude and the width of the envelop soliton.